A new material is developed
Members of the KiOR R&D team, though stymied by the troubles with HTC, developed a novel theory that the HTC material might be modified to address these shortcomings.
Stamires, working with KiOR R&D manager Mike Brady, a catalyst technology expert, asked CPERI chief Dr. Lappas to calcine (or heat treat) to at high temperature a sample of HTC, for sufficient time to completely destroy the crystalline structure and porosity.
Stamires recalls:
“This high temperature treatment transformed the original crystalline Hydrotalcite to a new material of the Spinel class, which exhibited very low pore volume and surface area, high bulk density, and low catalytic activity, and it was a totally different material to the original Hydrotalcite. When tested in the KCR Pilot Plant, as a heat transfer medium and also as a catalyst for biomass liquefaction to produce Bio-oil, this new material having the Spinel crystal structure, produced much more Bio-oil, with a reasonable low oxygen content, than it’s precursor Hydrotalcite.
“This material, with Spinel–like structure, exhibiting bi-functional properties, specifically, as a heat conductor and as a catalyst that proved to be a useful material for use by itself or in combinations with other materials in biomass thermo-liquefaction process.”
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